High partial pressure h2s pipelines pipelines, piping and. Sulfide stress cracking is the worst type of corrosion in the presence of hydrogen sulfide. Materials in the sour environment are susceptible to sulfide stress corrosion cracking ssc and hydrogeninduced cracking, hydrogen embrittlement and exfoliation hehic that leads to various modes of failure including stepwise cracking, hence the importance during the design stage on material selection. Hic in welding cold cracking haz cracking moisture n org compounds r primary sources of h. This part of ansinace mr0175iso 15156 addresses all mechanisms of cracking that can be caused by h 2 s, including sulfide stress cracking, stress corrosion cracking, hydrogen induced cracking and stepwise cracking, stressoriented hydrogen induced cracking, soft zone cracking, and galvanically induced hydrogen stress cracking. Jun 03, 2018 hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms. The critical partial pressure of h 2 s for hydrogen induced cracking to occur is about 0.
Specifying valves for hydrogen service valve magazine. Stressoriented hydrogen induced cracking sohic is a common, insidious form of wet h2s cracking. Hydrogen induced cracking is also known as cold cracking, delayed cracking or underbead cracking. A comparative study of hydrogeninduced cracking resistances of api 5l b and. Hightemperature hydrogen attack is also referred to as hot hydrogen attack or decarburization. H ydrogen induced cracking hic is a far too common type of failure. Aug 09, 2016 detection, characterization and sizing of hydrogen induced cracking in pressure vessels using phased. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogen induced cracking hic, describes the embrittling of metal after being exposed to hydrogen. Detection, characterization and sizing of hydrogen induced cracking in pressure vessels using phased array ultrasonic data processing article pdf available december 2016 with 380 reads. Hic steel hydrogen induced cracking supplier company. As we know that both form of cracking are due to the absorption of atomic hydrogen that. Ductility is the ability to deform permanently prior to fracture, and it is. Hydrogeninduced cracking hic is still a challenging issue that requires. Material considerations when working with hydrogen 3.
Over time, the metal becomes so brittle that it cracks. While these metals may normally be ductile in nature, the presence of hydrogen in a corroded environment can cause it to crack. This part of ansinace mr0175iso 15156 addresses all mechanisms of cracking that can be caused by h 2 s, including sulfide stress cracking, stress corrosion cracking, hydrogeninduced cracking and stepwise cracking, stressoriented hydrogeninduced cracking, soft zone cracking, and galvanically induced hydrogen stress cracking. It is made up of a series of hic hydrogen induced cracking cracks that are stacked perpendicularly in the direction of through wall cracks and driven by high residual or applied stresses.
Hydrogen induced cracking steel features, applications. Abstract h 2 s gas in the crude oil or natural gas causes hydrogen degradation such as hydrogen induced cracking hic and sulfide stress cracking ssc. Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking mechanism. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process environments. What is nace mr0175iso 15156 steel pipe and fittings. H 2 s gas in the crude oil or natural gas causes hydrogen degradation such as hydrogen induced cracking hic and sulfide stress cracking ssc. This equality arises from the fact that in an ideal gas the molecules are so far apart that they do not interact with each other.
What is high temperature hydrogen attack hthahot hydrogen. Hydrogen induced cracking of subsea duplex stainless steel twi. Hydrogen embrittlement and stress corrosion cracking. Hydrogen induced cracking hic remains a prominent issue for oil. In addition to ph and h2s partial pressure, test duration is another. Specificationsgrades asmeastm saa 516 grades 606570.
Thus hydrogen induced blistering can be seen as a special case of the plane pressure mechanism of hydrogen embrittlement, where high pressure hydrogen forms in. For hydrogen induced cracking to take place, individual hydrogen atoms must cluster at the surface of the metal to create hydrogen molecules. The blistering damage tends to form parallel to the surface and to the direction of hoop stress. High temperature hydrogen attack htha, also called hot hydrogen attack, is a problem which concerns steels operating at elevated temperatures typically above 400c in hydrogen environments, in refinery, petrochemical and other chemical facilities and, possibly, high pressure steam boilers. Steel materials that selected or qualified using nace mr0175iso 15156 are resistant to cracking in defined h2scontaining environments in oil and gas production, but are not nesessarily immune under all. The mechanism was initially proposed by zapffe and sims. For example, the percentage elongation after fracture of type304ss in room temperature hydrogen gas of 75 mpa decreases to around 30% of that in air while the. Hydrogen induced cracking steel features, applications and. When metal is subjected to tensile stress with high level of hydrogen content, hydrogen induced cracking occurs. Detection, characterization and sizing of hydrogen induced cracking in pressure vessels using phased.
Stress corrosion cracking behavior of nickel base alloys. This barcode number lets you verify that youre getting exactly the right version or edition of a book. This is a type of deterioration which can be linked to corrosion and corrosioncontrol processes. Detection, characterization and sizing of hydrogen induced.
Sulfide stress cracking is a function of hydrogen sulfide concentration as low as ppm, hydrogen sulfide partial pressure, stresses, material yield strength, temperature and ph. The methane molecules create a pressure which leads to embrittlement and even cracking of the metal. Hydrogeninduced cracking also referred to as cold cracking, is caused by the diffusion of hydrogen in the crystal lattice of haz near the fusion boundary. Effects of h2s partial pressure and ph of test solution on the hydrogen induced cracking of linepipe steels wan keun kim, seong ung koh, kyoo young kim, boo young yang, ki bong kang dept. High temperatures, large chloride content and partial pressure of h2s and small ph make the. If you recall, we mentioned you need all three factors to be present in order to have hic. High partial pressure h2s pipelines pipelines, piping. The stress which a structural material is able to withstand is conditioned by its ductility. May 19, 2009 susceptibility to hydrogen blistering and hydrogen induced cracking can be apportioned to the quality of the steel plate used. Definition of hic in the acronyms and abbreviations directory.
However, it may take longer for the cracks to grow to suf. Equivalently, low temperature hydrogen induced cracking was also noticed in inconel 718. This damage is localized and requires careful scanning for detection. Factors influencing hydrogen induced cracking welding. Furthermore, the risk of hydrogen induced cracking is present even at partial pressure of h 2 s pph2s below 0. Susceptibility to hydrogen blistering and hydrogen induced cracking can be apportioned to the quality of the steel plate used. This clustering produces pressure in the metal which results in the metal losing ductility, toughness and tensile strength. Material and metallurgical parameters were investigated. This micrograph shows intergranular cracking caused by high temperature hydrogen attack in a c0. It is a complex process that is not completely understood because of the variety and complexity of mechanisms that can lead to embrittlement. The original and subsequent editions of nace mr0175 established limits of h 2 s partial pressure above which precautions against sulfide stresscracking ssc were always considered necessary.
Sour gas h2s testing of dicrest hic resistant steel plates using test solution a the most common grades of hic resistant steel plate is a516 to asmeastm standards. Abstract as a first step, a literature survey was undertaken on hydrogen induced cracking hic phenomena. Sulfide stress cracking ssc also known as sour gas cracking sour gas. Daltons law expresses the fact that the total pressure of a mixture of gases is equal to the sum of the partial pressures of the individual gases in the mixture. Factors influencing hydrogen induced cracking welding answers.
For example, nace mr0175iso 15156 2 permit the use of higher strength. Material considerations for sour gas systems webex presentation february 10, 2016. A read is counted each time someone views a publication summary such as the title, abstract, and list of authors, clicks on a figure, or views or downloads the fulltext. It involves atomic hydrogen, which is the smallest atom, that diffuses into a metallic structure. Effect of hydrogen partial pressure on the hydrogen embrittlement.
Hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms. Sohic is a type of cracking that can easily lead to failure and needs to be mitigated. Stressoriented hydrogen induced cracking listed as sohic. Effects of h2s partial pressure and ph of test solution on. When combined these subscripts are applied recursively. They also provided guidance for the selection and specification of sscresistant materials when the h 2 s thresholds were exceeded. Sour gas h2s testing of dicrest hic resistant steel plates using test solution a the most common grades of hic resistant.
It is also called hydrogen assisted cracking hac and delayed cracking since it does not occur right after welding, but a few hours or days after the weld has completely cooled down to ambient temperature. For example, in boiler tubes, hydrogen damage is caused by a corrosive reaction between steam and steel, resulting in decreased material strength and localized corrosion. Hic resistant steel plate is used by boiler makers and fabricators when hydrogen induced cracking is a big risk. In the gas phase, a stream is sour if the h2s partial pressure exceeds 0. This pressure is added to applied stress and thus lowers the apparent fracture stress. Effects of h2s partial pressure and ph of test solution on the. Hydrogen induced cracking of hard materials zthe refining industry has had very few cases of hydrogen related cracking in pure hydrogen service. Another type of hydrogen corrosion, stressorientated hydrogen induced cracking sochic, is normally found in the base metal adjacent to the weld, where the stress point is highest due to the internal pressure of the.
Hydrogen induced cracking hic testing of low alloy steel in sour. High partial pressure h2s pipelines drillernic petroleum 15 apr 05 05. Also known as sour service, issues including hydrogen blistering, hydrogen induced cracking hic and stress orientated hydrogen induced cracking sohic are caused by the aqueous hydrogen charging of the steel. Materials in the sour environment are susceptible to sulfide stress corrosion cracking ssc and hydrogen induced cracking, hydrogen embrittlement and exfoliation hehic that leads to various modes of failure including stepwise cracking, hence the importance during the design stage on material selection. It involves the ingress of hydrogen into a component, an event that can seriously reduce the ductility and loadbearing capacity, cause cracking and catastrophic brittle failures at stresses below the yield stress of susceptible materials. Unfortunately, the term hydrogeninduced cracking, usually abbreviated as hic, has been introduced to designate cracking sometimes encountered in pipelines or vessels as a result of hydrogen picked up in. We will now go over how to prevent hic from happening. H2s partial pressures and the lowest ph values aqueous medium acidities. Sulfide stress cracking ssc vs hydrogen induced cracking hlc posted in refining, hydrocarbons, oil, and gas. Hydrogen stress cracking occurs when hydrogen penetrates highstrength or hardened metal in a state of tensile stress. Unfortunately, the term hydrogen induced cracking, usually abbreviated as hic, has been introduced to designate cracking sometimes encountered in pipelines or vessels as a result of hydrogen picked up in.
Stressoriented hydrogeninduced cracking hydrogeninduced craking galvanically induced hydrogen stress cracking. Sandia national laboratories is a multi program laboratory managed and operated by sandia corporation, a wholly owned subsidiary of lockheed martin corporation, for the u. Unfortunately, all three phenomena reveal themselves in. This charging can cause blistering and embrittlement, which is potentially disastrous in carbon steel pressure vessel environments. The significance of these failures has led to research aimed at defining critical conditions for hisc, to allow confident design of components in future. For corrosion resistant alloys cras there is now pph 2 s low limit, which means precautions need to be taken whenever the possibility of h 2 s is present. Sulfide stress cracking an overview sciencedirect topics. Preventing hydrogen induced cracking welding answers. Pdf hydrogen induced cracking safe materials operating limits. The literature sources suggested a variety of methodologies.
Stress corrosion cracking scc and sulfide stress cracking ssc are the most. It occurs in carbon and lowalloyed steels exposed for an extended period to hydrogen under high pressure and at high temperature. In the presence of h 2 s, hydrogen atoms originating from the cathodic reduction reaction driving the anodic dissolution reaction can diffuse into the steel, resulting in cracking mechanisms such as hydrogen induced cracking hic, sulphide stress cracking ssc and stressoriented hydrogen induced cracking sohic. Hydrogen induced cracking hic is a failure mechanism resulting in sudden exposures and cracks due to growing laminations inside the base material and welds.
Sulfide stress cracking ssc vs hydrogen induced cracking. Incoloy 825 is superiorly immune to stainless steel grade 316 in the chloride media due to larger content of nickel. Aug 02, 2014 the entrapped hydrogen makes cavities in metal that results in cracking due to weak ductility and tensile strength. Sep 07, 2009 the methane molecules create a pressure which leads to embrittlement and even cracking of the metal. Processes or conditions involving wet hydrogen sulfide, i. Material selection for sour service environment pipeline.
Hydrogen induced cracking is a mechanical fracture caused by penetration and diffusion of atomic hydrogen into the internal structure of steel, which changes into molecular. The effect of the partial pressure of h2s on the permeation of. Cracking occurs due to a significant loss in ductility. A small number of duplex and superduplex stainless steel components have failed in subsea service due to hydrogen induced stress cracking hisc. The equilibrium pressure of the molecular hydrogen in the void, which is in contact with the atomic hydrogen in the surrounding metal, is great enough to rupture any metal or alloy. Stressoriented hydrogen induced cracking hydrogen induced craking galvanically induced hydrogen stress cracking. Hydrogeninduced cracking is also known as cold cracking, delayed cracking or underbead cracking. Hydrogeninduced cracking an overview sciencedirect topics. What is the minimum partial pressure of h2s that requires. Hydrogen compatibility of materials department of energy. Hydrogen embrittlement is mainly a problem in steels with ultimate tensile strength greater than 90 ksi, although a number of additional alloys are susceptible. Hydrogen cracking is also named as toe cracking or underbead cracking due to its location of occurrence. Effects of h 2 s partial pressure and ph of test solution on the hydrogen induced cracking of linepipe steels authors wan keun kim dept. The susceptibility of carbon steel to hic can be mitigated by controlling the chemical composition in particular reducing the concentration of manganese sulphide.
Hydrogen induced cracking hic is a common form of wet h2s cracking caused by the blistering of a metal due to a high concentration of hydrogen. Sulfide stress cracking ssc vs hydrogen induced cracking hlc. The effect of different partial pressures of h2s ph2sph2s on the hydrogen. Sulphide stress corrosion cracking and hydrogen pressure induced cracking. The ssc of medium strength steels has been a continuing source of trouble in the oil fields, and from these troubles has evolved in international standards 6. Hydrogen induced decohesion model dissolved hydrogen lattice hydrogen reduces the cohesive strength of the lattice, i. The symbol for pressure is usually p or p which may use a subscript to identify the pressure, and gas species are also referred to by subscript. O ur last post factors influencing hydrogen induced cracking went over the factors that contribute to hydrogeninduced cracking. As we know that both form of cracking are due to the absorption of atomic hydrogen that is produced by. Dec 12, 20 with hydrogen damage, multiple metal degradation processes occur due to interaction with hydrogen. For the ssc cracking mode, a diagram defining different regions of. However, the test environment of nace tm028496 standard hic test method is unnecessarily severe than that of actual sour service conditions.
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